Download e-book for kindle: Biological identification: The principles and practice of by Richard J. Pankhurst

Download e-book for kindle: Biological identification: The principles and practice of by Richard J. Pankhurst

By Richard J. Pankhurst

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8) −E at each base pair n on the π stack. 9) for k = 1, 2, . . , L. 4) splits into two cosine bands such that E ∈ −t − 2 t2 + 2t↑ , −t + t2 + 2t↑ 2 ∪ t− 2 t2 + 2t↑ , t + t2 + 2t↑ 2 . 74 eV are being used. Therefore, we will assume tqi = 2ti and set the energy scale by ti ≡ 1 for hopping between GC pairs. Furthermore, since the energetic differences in the adiabatic electron affinities of the bases are small [111], we choose εi = 0 for all i. The physics of the fishbone model was first discussed for poly(G)-poly(C) in [29].

D. A. A. Ratner and L. D. A. Siebbeles, J. Am. Chem. Soc. 127, 14894 (2005). 31. K. C. Grozema, C. M. A. Siebbeles, J. Am. Chem. Soc.

This discrepancy is not surprising since the charge transfer rates will be affected by the Coulomb interaction between the Sa−• anion and the hole generated in the system. 3. 2 Charge Transfer Through DNA 37 Fig. 8. Survival probability for sequences 4a–4d as a function of time in absence (top) and in presence (bottom) of the Coulomb potential of Sa•− the nucleobases. The survival probabilities calculated in the case, where the Coulomb interaction is included in the calculations, are shown in Fig.

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