This quantity bargains with chemistry of polyelectrolytes, specifically biocide guanidine containing polymers, discussing either synthesis of recent guanidine containing monomers of diallyl and acrylic nature and their constitution and research in their radical (co)polymerization and houses of latest (co)polymers. the 1st elements of the publication describe radical polymerization of those monomers and their co-polymerization with diallyldialkylammonium derivatives, positive factors in their kinetic habit in those procedures (for instance, polymerization charges, reactivity ratios) The sections on phycal chemical tools (IR, NMR, DSC ect.) are in particular vital for learning of constitution and homes of synthesized monomer and polymer compounds. The booklet is finely illustrated with approximately hundred unique figures, schemes and tables together with kinetics, NMR, IR spectroscopy, biocide and different info.
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This quantity bargains with chemistry of polyelectrolytes, specifically biocide guanidine containing polymers, discussing either synthesis of recent guanidine containing monomers of diallyl and acrylic nature and their constitution and research in their radical (co)polymerization and houses of recent (co)polymers.
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Additional info for Biocide guanidine containing polymers
Intermolecular interactions of monomer and (or) polymer molecules between each other and also their interaction with solvent are characteristic for it. It turned out that monomers containing ionized or functional groups undergoing the mediums effects often relate to such systems; and even if such groups are absent, then the interactions of growing radical with solvent are possible as a result of complex formation under the action of hydrogen bonds, etc. that influences on the dependence of kp of chain on structure of reaction solution often leading to deviation from equation 2.
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E. the magnitude characterizing the interaction between polymer and solvent molecules is changed especially sharply; at that the PVP molecules practically completely soluble in alcohol become insoluble in the presence of guanidine hydrochloride that is the consequence of blocking of pyrrolidone cycle oxygen by guanidine hydrochloride molecules leading to the increase of forces of inter-molecular association of PVP cycles at the expense of hydrophobic interactions. Moravetz and other authors [120, 136] studied the influence of various factors on protein denaturation in details established that various guanidine salts and also the urea exert strongly denaturation influence on proteins molecules under their introduction into the solution even in small amount ~ 1%.